FIZIKA A 8 (1999) 3 , 113-122

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ELECTRONIC PROPERTIES OF HYDROGEN-DOPED (Zr803d20)1-xHx
(3d = Fe, Co, Ni) METALLIC GLASSES

IVAN KOKANOVIĘ and JAGODA LUKATELAa

Department of Physics, Faculty of Science, University of Zagreb, Zagreb, Croatia
aInstitute of Physics, P. O. Box 304, Zagreb, Croatia

Dedicated to Professor Boran Leontię on the occasion of his 70th birthday

Received 12 November 1999; revised manuscript received 3 February 2000
Accepted 21 February 2000

The electrical resistivities of hydrogen-doped (Zr803d20)1-xHx (3d = Fe, Co, Ni; x £ 0.11) metallic glasses have been measured at temperatures between 2 K and 290 K. The increase of the room-temperature resistivity and its temperature coefficient are explained as a consequence of increased disorder due to hydrogen-doping. The temperature dependence of the resistivity has been analysed using theoretical models of weak-localisation and electron-electron interaction in disordered three-dimensional conductors. The hydrogen dopant is found to reduce effective electron diffusion constant, D, the spin-orbit scattering rate, tso-1, the superconducting transition temperature, Tc, and broadens the superconducting transition region. We discuss the effects of different hydrogen environments on Tc of (Zr803d20)1-xHx metallic glasses.

PACS numbers: 74.70.-b, 75.20.-g
UDC 537.312, 538.95
Keywords: electrical resistivity, metallic glasses, (Zr803d20)1-xHx (3d = Fe, Co, Ni; x £ 0.11), hydrogen-doped, disordered three-dimensional conductors, electron diffusion constant, spin-orbit scattering, superconducting transition temperature
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